• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    A heat pump circuit has a compressor (C) which compresses a working fluid from a gas in a first state (1) with a low pressure and a low temperature to a gas in a second state (2) with a high pressure and a high temperature, wherein a first subflow of the working fluid is passed in a main circuit (Main) and is condensed into a gaseous/liquid mixture upon passage of a condenser (COND) and assumes a third state (3) by the working fluid delivering heat in the condenser (COND) to a first medium belonging to a heat cycle, and said first subflow of the working fluid is expanded in an evaporator (EVAP) and thereby returns to a gas in the first state (1) by absorbing heat from a second medium in a collector circuit connected to the evaporator (EVAP), whereupon the working fluid is returned to the compressor (C) and completes the cycle again, and wherein a second subflow of the compressed working fluid is expanded from the second state (2) that prevails at the outlet of the compressor (C) and is passed in a converting circuit (Transf) to an energy converter (TG) for converting the energy contents in the second subflow of the working fluid that traverses the energy converter (TG) into electrical energy, whereafter the expanded working fluid from the outlet of the energy converter is returned to the compressor (C) according to any of a) after passage of the evaporator (EVAP) for further expansion, b) directly back to the compressor (C) after expansion in the energy converter (TG) from the second state (2) to the first state (1).
    公开号:SE1230028A1
    申请号:SE1230028
    申请日:2012-03-20
    公开日:2013-09-21
    发明作者:Hardy Hollingworth
    申请人:Energihuset Foersaeljnings Ab Hardy Hollingworth；
    IPC主号:
    专利说明:

    [6] With globally rising prices for energy of various kinds, heat pump solutions have increased sharply in recent decades and a lot of development and resources are being invested by various actors to make heat pumps more efficient. Today, for heat pumps, heat factors (COP values) are achieved that are around 5. This means that the heat pump delivers optimally 5 times as much energy as it consumes. Such optimal values can be achieved at e.g. geothermal heat pumps, where geothermal heat is used as the cold source to heat consumers with low temperature requirements, e.g. for underfloor heating in homes.
    [7] Today, great efforts are being made to further increase the efficiency of heat pump systems.
    [8] In the prior art, a heat pump is used in a circuit for a heat pump, which is a medium which, during the cycle in the heat pump, is converted between different states of liquid, liquid / gas mixture and gas. The work genom uiden undergoes the cycle by in a first step in gaseous form from a first state with low pressure p] and low temperature t] being compressed to a second state with high pressure ph and high temperature th. Thereafter, the working fl uiden is heat exchanged in a condenser where the working fl uiden is cooled by a first medium belonging to a heating circuit and thereby obtains a third state with a pressure pm and a temperature tm, whereby p] <pm <p], and t] <tm <th. The working medium is then passed on to an evaporator and heat exchanged therein with a second medium belonging to a collector circuit, where this second medium emits heat to the working medium, whereby the working medium expands and substantially returns to the pressure and temperature prevailing in the first state.
    [9] The described prior art can be exemplified by means of a heat pump which absorbs heat from, for example, bedrock and emits heat in a heating system for e.g. a dwelling. In such a heat pump, the necessary work in compression of the working fluid is usually supplied by means of an electric motor-driven compressor, which here is said to supply the power P to the heat pump circuit. During the cycle, the working flow at the most optimal utilization, when the heat factor amounts to 5, will emit an effect 5P in the condenser to the first medium which passes through a heating circuit, which is used in said heating. 10 15 20 25 30 35
    [10] During the passage of the condenser, the working fluid is cooled and will then, as mentioned, assume a state of a gas / liquid mixture. This mixture is passed on via a throttle valve to the evaporator, whereby the mixture is substantially given liquid form, after which the working fluid in liquid form now expands to a working fluid in gaseous form. The heat of vaporization required for the evaporation is in this case taken up from the second medium which also circulates in the evaporator for heat exchange with the working medium. The absorbed power in this example is 4P. The second medium passes through a collector circuit, which in the present example contains the second medium, which is suitably arranged to circulate in the rock for absorbing heat from the bedrock. In the known devices, compressor, condenser and evaporator are dimensioned in such a way that they optimally complement each other and deliver to the heating circuit the power required in the context.
    [11] When the working medium learns the compressor as a hot gas in a heat pump cycle and emits heat to the condenser, the temperature and pressure of the hot gas fall sharply, whereby the hot gas at least for the most part turns into liquid. There is still unused pressure and excess temperature left in the working room to be used before an expansion valve arranged upstream of the evaporator. The purpose of the expansion valve is to distribute a predetermined amount of working fluid to the evaporator, in such a way that the expansion valve is controlled to expand the liquid flow downstream of the condenser. The liquid is expanded in the expansion valve so that it is given lower pressure and lower temperature before the liquid is expanded to steam in the evaporator.
    [12] Proposals for new, alternative solutions for utilizing a heat cycle in heat pump systems are given e.g. in the publications: J P2005 172336, WO 2011059131, JP2007132541 and JP 2009216275 all show a turbine that uses excess energy in the cycle and converts this into electrical energy. The turbine is located between the condenser and the evaporator. It can be noted here that in these cases the turbine is connected serially in the circuit with the working fl uiden. Said document discloses solutions which are intended to convert the above-mentioned excess of temperature and pressure downstream of the condenser into electrical energy by a turbine connected to a generator replacing the expansion valve. However, it is very difficult to get a turbine to operate during the prevailing conditions of the working conditions between the condenser and the evaporator.
    [13] It is an object of the present invention to provide a heat pump cycle which demonstrates a more efficient use of available energy in a heat pump system. 10 15 20 25 30 35 DESCRIPTION OF THE INVENTION NO
    [14] The present invention is a modification of a heat pump circuit according to the prior art. In this case, the focus has primarily been on arranging the heat pump circuit with certain means so that more heat is absorbed from the collector circuit at a plant with a predetermined heating / cooling need.
    [15] The invention can be exemplified generally as follows. It is assumed, as in the previous example according to the prior art, that the power requirement in a heat circuit for which the heat pump is dimensioned amounts to SP. Instead of, as in the prior art, laying out the generator to supply the power IP to the compressor, according to the invention the generator for the power 2P is dimensioned to give an illustrative example. At the heat factor 5, the power that the heat pump can deliver will grow to 10P. The absorbed power in the collector circuit grows to size 8P. Half of the power that the heat pump can deliver is carried according to the example to the heating circuit where the required power SP can be transferred to the first medium in the heating circuit. The remainder of the extracted power 10P from the heating circuit, i.e. SP, becomes available via the bypass in the conversion circuit at the turbine and is thus delivered as useful energy to an electricity generator which delivers the electrical energy mentioned. 10 15 20 25 30 35 The power output from the electricity generator is determined, among other things. of the efficiency of the package turbine / generator, hereinafter referred to as conversion unit. If it is assumed that this efficiency is 50%, then the delivered electrical power from the heat pump circuit will theoretically amount to 2.5P. Since a larger fl fate of working fl uid will pass the evaporator than is the case in the referenced corresponding conventional heat pump circuit, the evaporator needs to be upgraded to handle larger effects compared to the example according to the invention.
    [16] From what is shown according to the aspect of the invention, in the event of an increase in the power supplied to the compressor in the heat pump circuit, in a plant with a predetermined power requirement, a larger amount of energy will be recovered from the collector circuit. Of course, according to the invention, the second medium which supplies heat to the evaporator needs to have a sufficient energy content to be able to assist with the increased power output required in the evaporator. In the case of a plant for the extraction of rock heat, for example, two boreholes may be required at a certain distance from each other, in the case of such a plant where today only one borehole is required.
    [17] According to one aspect of the invention, there is provided a method having the features of claim 1. A device utilizing the method is presented in the independent device claim 3.
    [18] Further embodiments of the invention are presented in the dependent claims.
    [19] An advantage of the conversion unit according to the invention is that it enables the utilization of a previously not fully utilized resource in the form of an excess of pressure and heat in the heat pump circuit.
    [20] Further advantageous embodiments of the invention are shown in the detailed description of the invention.
    [21] To realize the invention, a number of embodiments of the invention are presented, which are also produced with the aid of the accompanying drawings.
    [22] A main principle of the invention is shown in Fig. 1. The figure shows a complete heat pump according to the invention including a conversion circuit which has been added in relation to the prior art. A refrigerant, here called working fl uid, circulates in the main circuit, called the Main, and in the conversion circuit, called the Transf. The working time can be selected depending on the use of the heat pump. Different types of work fl uider can be considered for, for example, heating purposes and cooling systems. An example is R407C, which is used i.a. in geothermal heat pumps.
    [23] In the following, the description is directed to a heat pump used in heating homes based on energy extraction from bedrock, lake or land. The examples given here regarding pressure, temperatures or other parameters are referred to here as a heat pump of that kind. If another use of the heat pump according to the invention comes into question, this means that other values of parameters may become relevant.
    [24] Here is an overview of the data data uiden data at its course through the heat pump cycle.
    [25] According to the invention, a first part fl of the working fl uiden, now in the form of hot gas, is passed on in the main circuit Main to a condenser CON D. The condenser is built as a heat exchanger and in this example, where the heat pump heats a home, through the surface condenser COND of a first medium circulating in a heating circuit Q, which may be radiators or underfloor heating coils.
    [26] From the condenser, the working flow is passed on in the main circuit Main to an EVAP evaporator. The EVAP evaporator also comprises a heat exchanger which in this case absorbs heat from a second medium, a brine medium, which circulates in a collector circuit Coll. The second medium (brine medium) consists of a medium substantially in liquid phase, for example a spirit-water solution, which in the case of rock, lake or ground heat circulates in a loop (collector circuit) to absorb heat from the rock, the lake or the ground in a known way.
    [27] The collector circuit runs through the evaporator EVAP and forms in it a heat exchanger structure together with loops of the main circuit Main. The working fl uiden in the main circuit Main enters the evaporator, essentially in the liquid phase, and here absorbs heat from the brine medium during heat exchange with this in the heat exchanger structure. Heat is supplied to the EVAP evaporator via the refrigerant medium which is introduced into the evaporator at its inlet Cm. This heat supplied via the collector circuit evaporates in this case the working till uid substantially in the liquid phase supplied to the evaporator. The heat of vaporization for the evaporation is taken from the brine. The refrigerant thus cooled is returned in the collector circuit to the heat source (rock, lake, ground) at the Cut outlet.
    [28] The control of the amount of working fl uid in gas / liquid phase that is allowed to enter the evaporator EVAP is normally controlled via an expansion valve Exp between condenser and evaporator, which as mentioned lowers the temperature and pressure of the working AP uid which is essentially in liquid form. The function of the heat pump circuit Main described so far shows in principle the function of a heat pump according to known technology. According to this prior art, some energy is lost, as the compressor C operates even when overpressure already exists in the circuit before the expansion valve Exp.
    [29] According to an aspect of the invention, a second part fl of the working i uiden in a bypass is led past the condenser COND with outlet of the working fl uiden at a first shunt valve S1 downstream of the working fl uiden outlet from the compressor C. This part fl of the flow flows in the conversion circuit Transf. In this part fl of the Transf conversion circuit a conversion unit TG is placed, which is traversed by the part fl before it is returned to the main circuit Main, either via a third shunt valve S3 to the evaporator EVAP inlet downstream of the expansion valve Exp, or via said third shunt valve S3. Directly back to the compressor C. The third shunt valve can during certain operating cases allow return to the main circuit Main according to both of these alternatives simultaneously, ie. return of part fl of the working arbets uiden from the conversion circuit to the main circuit Main both before and after the evaporator EVAP.
    [30] The compressor C can be a piston, scroll or screw compressor. The EVAP evaporator can in turn be of the indirect evaporator type and then usually consists of a plate heat exchanger. Alternatively, evaporation can take place directly in e.g. an evaporation loop for geothermal, sea heat or consists of an fl end battery for air. Preferably, the compressor C is a speed controlled DC compressor.
    [31] When using the conversion unit TG according to the invention, the evaporator can also have a shunted fixed evaporation process by supplementing with demand-controlled dilution with the working fl uid via the existing expansion valve Exp. This is done by the expansion valve being controlled by the value of the temperature absorption of the evaporator. By this method maximum evaporation is achieved, so that the compressor C is able to perform its work without risk of breakdown, due to so-called "liquid type".
    [32] The principle of the invention is based on creating a higher fl fate of working fl uid through the heat pump circuit than is justified based on the predetermined need for a particular installation, as in the examples where the predetermined need may be the power requirement in a heating circuit for heating purposes. This is achieved by introducing the extra part fl destiny which according to the invention passes the conversion unit TG parallel to the part fl destiny in the ordinary heat pump circuit adapted to the predetermined need, at e.g. heating, according to known technology. In order for this to be arranged, it is required that the pressure and temperature of the part fl through the conversion circuit Transf have essentially the same values as the values that the part fl of the main circuit Main has at the points where the part fl fins are reunited, which occurs as above at one or both of the third shunt valve S3 both outlets, ie. at any of the evaporator inlets resp. outlet.
    [33] During certain operating cases, it may be necessary to link the main circuit Main upstream of the capacitor C with the conversion circuit Transf in order to transfer working fl uid from the conversion circuit to the main circuit. A non-return valve V prevents the working fluid from flowing in the opposite direction.
    [34] Figure 1 also shows a control unit CONTR. This control unit monitors the operating cases that may occur for operation of the heat pump. Thus, the CONTR control unit controls the start and stop of the compressor C, controls the fl fates of the working fl uid at the shunt valves S1, S2, S3, the expansion valve Exp, and controls the voltage regulator REG which controls the output voltage from the generator G. Control of a heat pump is conventional technology. the function of the control unit is not reported in detail here.
    [35] The conversion unit can be placed in different ways in the heat pump circuit and is then given slightly different designs, but utilizes said pressure / heat excess. An embodiment variant is to integrate the turbine part and the compressor / electric motor, whereby these are mechanically relieved and thus require lower energy for operation. In this embodiment, no generator part is required, which is a simplification in itself, but which requires a reconstruction of the compressor unit.
    [36] Calculation example An example of a dimensioning of a heat pump circuit according to the invention is presented here. The example is only intended to shed more light on the idea of the invention and may only be perceived as a principled embodiment and as such cannot be used as a basis for an argument against the invention. As such an example, a theoretical calculation of parameters at a heat pump circuit according to the invention is shown here based on a heat pump according to the Carnot principle: 10 15 20 25 30 35 10 Prerequisites: - Determined heat demand at a plant and extraction of Water with an average temperature of +40 ° C (T 1) at Vu, in the heating circuit at the condenser COND: 8 kW (peak power).
    [37] The conversion unit TG can be designed as shown in a cross section in Fig. 2.
    [38] A further exemplary embodiment is shown in Figure 3.
    [39] Functional description of the heat pump circuit.
    [40] A heat pump constructed according to the method can be given alternative designs. As an example, the evaporator EVAP and the conversion circuit TG can be integrated with each other, for example by the evaporator constituting the outer jacket of the conversion unit. Through this design, all excess heat from the TG conversion unit can be transferred to the EVAP evaporator, which thereby utilizes additional excess energy. A construction of the EVAP evaporator according to this principle is shown in Fig. 4.
    [41] Theoretical calculations when using the conversion possibilities of the conversion unit in a heat pump circuit according to the aspects of the invention, reported here based on the application according to Figure 4: According to Mollier diagram applied for the working flow R407 C, this medium in the form of a hot gas with pressure 24 kPa and temperature approx. ° C a temperature that amounts to approx. + 20 ° C if the pressure is reduced to approx. 4 kPa, when the medium is proposed to pass through a 2-stage turbine that drives a high-speed generator. A commercially available speed-controlled DC-powered heat pump that has a rated power of 0-17 kW has, for example, a maximum hot gas fl capacity of approx. 18 kbm / h according to technical specification from manufacturers. This means a maximum hot gas på of about 300 liters / rnin or about 5 liters / sec. The energy content of this “mass fate” is divided by the shunt valve S1, which is a shunt valve controlled by the CONTR control unit. Consequently, if the 2-stage turbine lowers the gas pressure by 24 kPa to about 4 kPa, more than 80% of the energy content of the excess pressure in the Transf conversion circuit should be converted into kinetic energy in the 2-stage turbine T and provide heat generation in the entire TG conversion unit. We assume in the example that pressure and temperature account for equal parts in this process as a Mollier diagram shows. When a heat pump circuit is arranged according to the embodiment in Fig. 4 with the conversion unit TG integrated / enclosed in the evaporator EVAP, virtually all heat losses in the conversion unit TG will be supplied to the evaporator EVAP, which significantly increases the evaporation temperature for the entire heat pump circuit Main + , i.e. both from the condenser COND via the expansion valve Exp (normal route according to known technology) + the “direct gas mixture” which has passed via the integrated conversion unit TG. With the correctly dimensioned evaporator EVAP and collector circuit, a significantly larger energy uptake will then be made from the collector circuit, which allows the extraction of electrical energy via already known and functioning cooling / heat pump technology. To utilize the remaining pressure / temperature, ie. energy content after condenser outlet / passage, it is advantageous to connect a subcooler Ul in series in the incoming line Cm to an evaporator in the collector circuit, as the expansion valve Exp does not let through work fl uid which has too high a pressure / temperature value and thus constitutes an unnecessary source of loss. The same connection method can also be used with a subcooler U2 placed in the outgoing line Cu, in the collector circuit to lower the temperature of the working flow further after passing the turbine T and thus squeeze more energy out of the part fl out of the turbine T before entering the evaporator EVAP. This presupposes that it is economically justified to further optimize the evaporation temperature of the interconnected parts fl of the working fl uiden, sumagas fl the fate (at 3), which must return to the suction side of the compressor C. In situations where too much fate has been created through the turbine T, excess is shunted / bypassed via controlled shunt valve S3 past the EVAP evaporator. This bypassed excess is linked to the discharge from the EVAP evaporator and fed to the suction side of the compressor C. The compressor is then "pressure-relieved", which means that energy consumption decreases, as minimal pressure differences are thereby created.
    [42] As mentioned earlier, the heat pump circuit described herein can also be used in refrigeration machines. In these contexts, it is the cooling of an external medium at the evaporator (EVAP) that is sought, e.g. air as the second medium, which in the evaporator (EVAP) passes cooling coils with working fl uid that absorb heat from the air. If the invention presented here is to be used in cooling machines, the dimensioning of the circuit is instead based on the cooling power sought at the evaporator (EVAP), instead of as stated in the examples above regarding heating purposes, where it is the power requirement in the heating circuit at the condenser that is governing in the design of the circuit.
    权利要求:
    Claims (1)
    [1]
    A patent in a refrigerant circuit comprising a working circuit which in the circuit from a first state (1) with low pressure p1 and low temperature t1 is compressed to a second state (2) with high pressure p1, and high temperature tll, after which the working fl uiden is cooled and thereby occupies a third state (3) with a pressure pm and a temperature tm, whereby pl <pm <pl, and tl <tm <tll, and where the working fl uiden is subsequently expanded to substantially return to the pressure and temperature prevailing in the first state (1) before the working fl uiden is compressed again in the cycle, characterized in that - a first part fl of the compressed working fl uiden is heat exchanged in a condenser (COND) so that said cooling of the working sker uiden takes place via a first medium belonging to a heating circuit (Q) with loops through the condenser, where the first medium cools the working som uiden which thereby occupies the third state (3), and where the working fl uiden is passed on to an evaporator (EV AP) and in this heat is exchanged with a second medium belonging to a collector circuit (Coll), where this second medium emits heat to the working medium, whereby the working medium undergoes said expansion and substantially returns to the pressure and temperature prevailing in the first state (1), a second part fl of the compressed working fl uides undergoes said cooling and said expansion from the second state (2) upon passage through a turbine (T) and is returned to the first state (1) in the cycle by one of: a) further expansion in the evaporator (EVAP), b) expansion in the turbine (T) from the second state (2) to the first state (1), c) expansion according to both a) and b), and - the turbine (T) drives a generator (G) which converts work obtained during the expansion of the working i uiden in the turbine (T) into electrical energy. Method according to claim 1, wherein: - the distribution of work fl uid to the first resp. to the second part fl fate, and - return of work fl uid in the second part fl fate to the first state (1) according to one of the options a), b) and c), is controlled by means of a control unit (CONTR) via controllable shunt valves (S1, S2, S3 ). Device comprising at least one compressor (C), a condenser (COND), an evaporator (EVAP) and a turbine (T) in a circuit which, through a working surface, is characterized in that: the compressor (C) compresses the working surface of a gas in a first state (1) with low pressure p1 and low temperature t1 to a gas in a second state (2) with high pressure p11 and high temperature t11, a first part fl of the working pl uiden is passed in a main circuit (Main) and is condensed into a gas / liquid mixture upon passage of the condenser (COND) and thereby assumes a third state (3) with a pressure pm and a temperature tm by the working fluid emitting heat to a first medium belonging to a heating circuit (Q ), where the first medium is heat exchanged with the working fl uiden in the condenser (COND) and here it applies that pl <pm <ph and tl <tm <th, said first part fl of the working fl uiden is passed on from the condenser (COND), expanded in the evaporator (EVAP) and then returns to a gas in the first state (1 ) by absorbing heat from a second medium in a collector circuit (Coll) connected to the evaporator (EVAP), where the second medium is heat exchanged with the working medium, after which the working medium is returned to the compressor (C) and passes through the circuit again, - a second part the compressed working fl uiden is expanded from the second state (2) prevailing at the outlet of the compressor (C) and is carried in a conversion circuit (Transf) to a turbine (T) to convert energy content in the second part fl of the working fl uiden which passes through the turbine (T) into rotational motion , after which expanded working fl uid from the turbine outlet is returned to the compressor (C) according to any of: a) after passage of the evaporator (EVAP) for further expansion, b) directly back to the compressor (C) after expansion in the turbine (T) from the other the state (2) to the first state (1), c) according to both a) and b), - to the turbine (T) a generator (G) is connected to convert said rotational motion into electrical energy. Device according to claim 3, wherein the device is operated for different operating cases by means of a control unit (CONTR), which controls a first shunt valve (S1) for distributing the first and second part fl deserts of the working fl uiden, and which further controls a second shunt valve (S2) and a third shunt valve (S3) for selection of operating cases by returning working fl uid from the second part fl to the compressor (C) according to one of a), b) and c). Device according to claim 4, wherein a motor (M) driving the compressor (C) is speed-controlled, the control unit (CONTR) controlling energy supply to the compressor (C) through a control of the motor (M) for adapting the device to different operating conditions. Device according to claim 5, wherein the control of the amount of working fl uid in gas / liquid phase that is allowed to enter the evaporator EVAP is controlled by the control unit (CONTR) via a controllable expansion valve (Exp) between condenser (C) and evaporator (EVAP). Device according to claim 1, wherein the turbine (T) which is through the surface of the second part fl of the working fl uiden and the generator (G) driven by the turbine (T) are integrated and encapsulated in a common pressure-tight housing. Device according to any one of claims 1 to 6, wherein the turbine (T) which, through the surface of the second part del of the working fl uiden and the generator (G) driven by the turbine (T) are integrated and encapsulated in a common pressure-tight housing and where the evaporator (EVAP) is arranged to enclose the pressure-tight housing common to generator (G) and turbine (T), whereby the evaporator (EVAP) is arranged to utilize excess heat leaking from said pressure-tight housing. Device according to claim 7 or 8, wherein the turbine (T) has at least one turbine stage with at least one turbine rotor, wherein said at least one turbine rotor is rotated by the second part fl in the form of a hot gas, and further wherein the rotor of the generator (G) is mounted on the same shaft as the turbine (T) at least one turbine rotor, while the stator of the generator is preferably integrated with the pressure-tight housing. Device according to one of the preceding claims, wherein the electrical voltage generated by the generator (G) is transferred to a voltage regulator (REG), which is controlled by the control unit (CONTR) to regulate a voltage delivered from the voltage regulator (REG) in relation to the current operating conditions of the device. .
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    SE1230028A|SE536432C2|2012-03-20|2012-03-20|Heating cycle for transfer of heat between media and for generating electricity|SE1230028A| SE536432C2|2012-03-20|2012-03-20|Heating cycle for transfer of heat between media and for generating electricity|
    EP13764797.0A| EP2847522B1|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
    ES13764797T| ES2877298T3|2012-03-20|2013-03-19|Heat cycle for heat transfer between media and for electricity generation|
    PCT/SE2013/050305| WO2013141805A1|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
    DK13764797.0T| DK2847522T3|2012-03-20|2013-03-19|HEAT CYCLE FOR TRANSFER OF HEAT BETWEEN MEDIA AND FOR GENERATION OF ELECTRICITY|
    JP2015501627A| JP6194351B2|2012-03-20|2013-03-19|Thermal cycle for heat transfer and electricity generation between media|
    KR1020147026977A| KR102035367B1|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
    PT137647970T| PT2847522T|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
    US14/387,207| US9689599B2|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
    CN201380015546.8A| CN104204689B|2012-03-20|2013-03-19|Between medium, transmit heat and produce the thermal cycle of electric power|
    PL13764797T| PL2847522T3|2012-03-20|2013-03-19|Heat cycle for transfer of heat between media and for generation of electricity|
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